Method of purifying cyanide-containing waste water
专利摘要:
A method for treating a waste water containing cyanide ions, which comprises (1) adding a ferrous salt to the waste water to convert the cyanide ions in it to a precipitate of ferrous ferrocyanide and insoluble Turnbull's blue, (2) adding an alkali agent to the waste water to convert the remaining ferrous ion to Fe(OH)2, and (3) adding a ferric salt to this waste water to precipitate ¢Fe(CN)6!4- formed by addition of the alkali agent as insoluble Berlin blue. The method permits a very efficient removal of the cyanide ions from the cyanide ion-containing waste water. It is particularly suitable for the treatment of gas liquor which has been discharged from the step of quenching coke oven gas and treated with activated carbon and activated sludge. 公开号:SU828960A3 申请号:SU772550053 申请日:1977-11-30 公开日:1981-05-07 发明作者:Ивазе Тосио;Хасимото Теруо;Сибуя Юкихико;Харада Хироси;Игути Еуко 申请人:Ниигата Инджиниринг Ко,Лтд (Фирма); IPC主号:
专利说明:
additional stage of processing pa anneobmepnoy resin. F o r p l1 of the invention The method of purification of cyanide containing iodine, including the introduction of iron salts, followed by the separation of cyanide iron compounds, and with the fact that, in order to improve the degree of purification of the second process, in the wastewater solutions of ferric chloride, sodium hydroxide and ferric chloride are introduced in succession, and cyanide compounds of iron are separated by settling. Sources of information taken into account with expert. 1. Japanese Patent 49-18943, C. 02C 5/00, 14.05.74. 2. The US patent. No. 3788983, cl. C 02 C 5/02, 01/29/74 (prototics).
权利要求:
Claims (1) [1] Claim The method of purification of cyanide-containing waste iodine, including the introduction of iron salts, followed by separation of the cyanide compounds of iron, is distinguished by the fact that, p. In order to increase the degree of purification and simplify the process, solutions of ferric chloride, sodium hydroxide and ferric chloride are successively introduced into wastewater, and the cyanide compounds of iron are separated by settling.
类似技术:
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同族专利:
公开号 | 公开日 DE2753401C2|1982-11-25| FR2383888A1|1978-10-13| FR2383888B1|1982-04-30| DE2753401A1|1978-09-21| CA1089573A|1980-11-11|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US5893408A|1995-08-04|1999-04-13|Nautica Dehumidifiers, Inc.|Regenerative heat exchanger for dehumidification and air conditioning with variable airflow| MD4139C1|2010-06-28|2012-07-31|Государственный Университет Молд0|Process for neutralization of waste obtained from wine demetallization with potassium hexacyanoferrate |DE1286463B|1963-04-24|1969-01-02|Bucksteeg|Process for the detoxification of wastewater containing cyanide| CH545254A|1972-09-27|1973-12-15|Ciba Geigy Ag|Process for purifying waste water| ZA737730B|1972-10-26|1974-09-25|St Regis Paper Co|Process for reducing the organic carbon content and improving the color of aqueous plant effluents|US4211646A|1977-10-31|1980-07-08|Texaco Inc.|Waste water process| US4312760A|1980-02-19|1982-01-26|Neville Roy G|Method for the removal of free and complex cyanides from water| FR2854088B1|2003-04-23|2006-09-29|Inertec|METHOD FOR FIXING CYANIDES IN SOLID WASTE OR IN WATER| CN105399261B|2015-12-12|2018-02-13|李运华|A kind of processing method of low concentration electroplating cyanic waste water| CN112863611B|2021-01-14|2022-03-08|山东黄金矿业科技有限公司选冶实验室分公司|Method for determining iron salt dosage extreme value in cyanide-containing wastewater treatment by iron salt precipitation method| CN113908799B|2021-12-14|2022-03-08|山东省科学院生态研究所|Preparation method and application of magnetic Prussian blue nano clay|
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申请号 | 申请日 | 专利标题 JP3073877A|JPS5627118B2|1977-03-19|1977-03-19| JP3863677A|JPS5651835B2|1977-04-05|1977-04-05| JP10141577A|JPS5627119B2|1977-08-24|1977-08-24| 相关专利
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